1/16/2024 0 Comments Unity fbx exporter script support
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1/16/2024 0 Comments M12 fuel oscillating toolIf you want the highest torque and performance possible, there’s one clear choice. Model numbers and basic differentiating details are on the horizontal x-axis. The numbers for the torque specs are on the left, and speed specs on the right. The vertical y-axis labels are also color-coded to help guide you.īasically, compare red to red and blue to blue. If this is your first time seeing a two-axis chart, note that the scales are different. In the graphs featured on this page, above and below, the vertical y-axis values on the left corresponds to the maximum torque values for Milwaukee’s different cordless drill models, and the values on the right correspond to the maximum speed range values. The comparison chart above shows the maximum torque, and maximum no-load speeds.Īll of Milwaukee’s M12 and M18 cordless drills have 2 speed settings – low and high – and I feel it’s important to see how torque and speed compare between various models. Most tool users will start off their research by looking at a cordless drill’s maximum torque rating. Milwaukee Cordless Drill Torque and Speed Comparison Chart Please let me know if you feel there’s something missing that could help make this buying guide better, and also if you would like the same approach applied to different brands or types of tools. So, I’m approaching this post as if I were an end user looking to make sense of all of Milwaukee’s different cordless drill offerings for the first time.Īfter going over some comparisons and specs, I’ll offer my recommendations on the best Milwaukee cordless drills for different user requirements, or rather what I’d purchase for my own needs depending on what I’m looking for. There are plenty of Milwaukee cordless drill buying guides out there, but I haven’t seen a single one that would actually help me if I were researching a purchase. 1/14/2024 0 Comments Production tool high point ncProduced on a line adjacent to the press brake, the loading/unloading laser machine automation also has modular attributes. Both HRB models have options, like special gauging or sheet followers, that fabricators can add at the time of purchase or choose to add later.Īmada COO Mike Guerin, CMO Patrick Medlin and High Point Mayor Jay Wagner push a button to initiate the cycle of the company’s two-column bridge mill, which machines beams and side plates for press brakes. The plant will produce both stand-alone HRB press brakes as well as an HRB with an automatic tool changer (ATC). The plant now employs a little more than 50 people, and the company expects employment to rise as it ramps up production of its HRB, short for Hybrid Retrofittable Bending machine. “This is what bringing jobs back to the United States looks like.” “Upon completion of this campus, Amada will add about 200 good-paying jobs,” Medlin continued. High Point has become high tech, and the opportunities here are endless. Many furniture and textile jobs were offshored, and for nearly three decades we watched a skilled workforce struggle … But today the future is much brighter. “And we’ve seen many changes over the years. “It’s also known as the furniture capital of the world,” Medlin said. High Point has long been known as the “international city,” thanks to the large number of foreign companies that have set up U.S. “Without his vision and influence, Amada would not be manufacturing press brakes and automation in North Carolina.”ĭuring his subsequent speech, Medlin gave some perspective, not only about what the new campus means for the sheet metal fabrication business in the U.S., but also what it means to High Point and the broader Greensboro metro area. “He’s been the one with the foresight to build factories in China, Japan, and now in the U.S.,” Guerin said. The executive has spearheaded Amada’s global manufacturing strategy. and Yukihiro Fukui, CEO of Amada North America.įukui in particular gained special praise from speakers. (which completed the facility on time despite significant weather delays) Sandy Dunbeck, executive vice president of the High Point Economic Development Corp. 6.Īlso on hand were Patrick Medlin, chief manufacturing officer of Amada America Jay Wagner, mayor of the High Point Brett Goode, senior vice president of Gray Construction Corp. “Including the buildings here in North Carolina, Amada now has more than 1 million square feet of covered real estate in the United States,” said Mike Guerin, COO, Amada North America, during the official ribbon cutting Dec. In 2013 the company opened a laser cutting machine manufacturing plant in Brea, Calif. addition to its existing plant in Batavia, N.Y. The opening follows another manufacturing expansion earlier in 2019, when Amada Tool America completed a 19,000-sq.-ft. The North Carolina campus has Amada’s third manufacturing facility in the U.S. Carolina Technical Center, will open in 2020. Another building on the campus, the 62,000-sq.-ft. Seventeen months after breaking ground, Amada America officially opened its 190,000-square-foot Carolina Manufacturing Center in High Point, N.C. is becoming one of the strongest, most important sheet metal fabrication markets in the world. In early December came more evidence that the U.S. Executive VP Sandy Dunbeck and Gray Construction VP Brett Goode prepare to cut the ribbon, officially opening Amada’s North Carolina manufacturing plant. From left, Amada CMO Patrick Medlin, COO Mike Guerin, CEO Yukihiro Fukui High Point Mayor Jay Wagner High Point Economic Development Corp. 1/14/2024 0 Comments Reactivity of dienophiles17 Regarding the former, this is illustrated by the difference in the. Which dienes react more rapidly than A Enter the letters corresponding to your selections in the answer box. Using 1,3-butadiene ( A) as a reference, consider the relative reactivity of each in a Diels-Alder reaction with the dienophile maleic anhydride 1. Traceless Thioacid-Mediated Radical Cyclization of 1,6-Dienes. Diene Reactivity in the Diels-Alder Reaction Examine the diene formulas A through G. The dienophile \textit increasing reactivity is shown in the picture below. Illustrating the strategic value of this method for synthetic planning, the reaction of 4- and 2-vinylpyridines with a variety of benchmark dienes follows predictable trends of reactivity and regioselectivity commonly observed with conventional dienophiles (Fig. Cyclopropenes are small and highly reactive compounds however, their synthesis poses. The initial bonding interaction reflects this electron imbalance, with the two new sigma-bonds being formed simultaneously, but not necessarily at equal rates.Let's take a look at the structures of the given compounds in order to determine their reactivity as dienophiles in Diels-Alder reaction. Introduction The acceleration of Diels-Alder reactions by Lewis acid catalysts has had a tremendous impact in organic synthesis since its discovery by Yates in 1961.1 By coordinating with carbonyl-conjugated dienophiles, Lewis acids affect the reactivity and the diastereoselectivky outcome of the reaction. In its usual form, the diene component is electron rich, and the best dienophiles are electron poor due to electron withdrawing substituents such as CN, C=O & NO 2. For many acyclic dienes the s-trans conformer is more stable than the s-cis conformer (due to steric crowding of the end groups), but the two are generally in rapid equilibrium, permitting the use of all but the most hindered dienes as reactants in Diels-Alder reactions. The Diels-Alder reaction is a single step process, so the diene component must adopt an s-cisconformation in order for the end carbon atoms (#1 & #4) to bond simultaneously to the dienophile. Toward 3,6-dipyridyl-s-tetrazine in MeOH at 25 C, the strained derivative is 19 and 27 times more reactive than the parent trans-cyclooctene and 4E-cyclooct-4. It is the prototypical example of a pericyclic reaction. The Diels-Alder cycloaddition is classified as a process because the diene has four pi-electrons that shift position in the reaction and the dienophile has two. In organic chemistry, the DielsAlder reaction is a chemical reaction between a conjugated diene and a substituted alkene, commonly termed the dienophile, to form a substituted cyclohexene derivative. The chiral group in the template is labelled with. Cycloaddition reactions studied in this work between a chiral anthracene template ANT and eleven dienophiles 1 A to 3 C. The reactants used in such reactions are a conjugated diene, simply referred to as the diene, and a double or triple bond coreactant called the dienophile, because it combines with (has an affinity for) the diene. Chiral anthracene templates and dienophiles used for DA cyclo-additions. The Diels-Alder reaction is an important and widely used method for making six-membered rings, as shown on the right. The cycloaddition converts these pi-bonds into new sigma-bonds (colored green), and this transformation is then designated a cycloaddition, to enumerate the reactant pi-electrons that change their bonding location. In the hypothetical ethylene dimerization on the left, each reactant molecule has a pi-bond (colored orange) occupied by two electrons. The following diagram illustrates two cycloadditions, and introduces several terms that are useful in discussing reactions of this kind. SN1 and SN2 reactions - kinetics, order of reactivity of alkyl halides. This does not occur under normal conditions, but the cycloaddition of 1,3-butadiene to cyanoethene (acrylonitrile) does, and this is an example of the Diels-Alder reaction. Stability of conjugated dienes, Diel-Alder, electrophilic addition, free radical. Cyclopentadiene and cyclopropene are unusual, in that they exhibit rapid Diels-Alder reactivity despite their lack of activating electron withdrawing or. When this occurs, two pi-bonds are converted to two sigma-bonds, the simplest example being the hypothetical combination of two ethene molecules to give cyclobutane. Reactivity increase of dienophiles by change of the ester substituents into the acid chlorides: cycloaddition reaction of the diacid chloride of 3,10-hexacyclo 10.2.1.15,8.02,11.03,10. A cycloaddition reaction is the concerted bonding together of two independent pi-electron systems to form a new ring of atoms. The unique character of conjugated dienes manifests itself dramatically in the Diels-Alder Cycloaddition Reaction. This is especially helpful when playing on TV and mobile devices. Once you have configured several possible ways to make the call depending on the software version, one possibility is by pressing the power key five times in a row (in some models it is activated with three consecutive keystrokes), in case this option does not work in The lock screen should show the emergency text at the bottom, click on the word “Emergency” and you will be able to access the emergency contacts. Ubisoft Connect Fortnite Once you have completed account linking, you will no longer need to log in to your store account to play games when using GeForce NOW. Within this section you must configure the emergency contacts that you want to appear when activating the emergency call. On Android devices like the Nvidia Shield it is possible to quickly access emergency contacts without having to unlock the terminal.įirst of all you must configure emergency calls on your Shield, for this you must go to the device settings and search under “Advanced functions” or “Security and privacy” section “Send emergency message”, “Contacts of Emergency” or “SOS Emergency” varies depending on the version of the operating system and the customization layer of Nvidia. This feature does not enable single sign-on for your Epic Games account for all other Epic games you own. Your Nvidia Shield comes with pre-installed applications that you may not use and are taking up space in your 16 GB memory.Ĥ- Keep your Nvidia Shield updated to the latest software version, Android 4.4.2 (KitKat)| upgradable to 7.0 (Nougat) it is the version of the operating system with which it was released but possibly new versions have come out with performance improvements.Ħ- Install an antivirus or cleaning application.ħ- As a last option you can perform a format, factory reset or hard reset of your Nvidia. Our Epic Account linking feature enables single sign-on for Fortnite, which lets you play the game without having to log in to your Epic Games Account every time you launch a new Fortnite session on GeForce NOW. Check all downloaded applications you do not use and delete them.Ģ- Remove pre-installed applications. Unlike a computer or laptop, we cannot expand the RAM of a Nvidia Shield from 2 GB RAM which comes by default so we have to look for methods to improve its performance.ġ- Perform an unnecessary application cleanup. When I start streaming from my gaming PC to the HTPC Steam automatically mutes audio on the PC as soon as a. Connect power only for 2 hours (no HDMI), then plug in HDMI and do a cache reset. In case the same kind of issue is still occurring, move down to the next potential fix below. Launch Destiny 2 and see if the freezing issue has been resolved. ago Support gave me a typical bullshit support answer today: Unplug everything for 2-3 minutes. Once you’re inside the uninstallation screen, follow the on-screen prompts to complete the uninstallation operation. There are several methods to improve the speed of a Shield from Nvidia before resorting to acquiring a new model or resorting to more drastic methods. The only thing that fixes it is unplugging. 1/14/2024 0 Comments Cars and bidFor more information regarding this concern, see our policies. – Any complaints about the pictures and information on the vehicles.– Information concerning vehicles that have been sold at previous auctions.– Answers to technical questions about any of the vehicles at auction.Some information that we will not address: To get a closer look, click on the picture to enlarge it. Each vehicle has a picture and more detailed information so that you can get a better idea of what you are bidding on, including the make and model of the vehicle, the year it was made, the VIN #, how much mileage it has, and information on the title. Save up to 60 on hotels and rent cars from 8.99 / day in your favorite destinations. By clicking on the Auction List tab, you can see our new list of vehicles each week. Find the best deals on the cheapest hotels, cars & flights with Hotwire. Some of our vehicles have been donated from private parties, Oregon charities, and that have been impounded. If your early bids were not caught, we will always confirm if you want to outbid before moving on.Īt Speed’s Towing Auction we have vehicles that come from multiple sources.We will charge your credit card right when you get the winning bid on your vehicle.Should I use Bring a Trailer (BAT), Cars and Bids. You cannot bid without legitimate credit card information. Hey gurus - need your views: Looking to sell my 05 Honda S2k to finance a portion of the upcoming 5BW.Every vehicle sold online has a $20 processing fee.Each online vehicle has a 17% buyers fee attached.Because these auctions go fairly fast, we may not always see your IM with the new bid. That is when your new bid will become official. When your new bid appears green, you have to click the new green amount to accept the amount. If you are going to make a higher bid, you can IM the bid to us.The auctioneer will determine which bid to take between the present and online bids. Through online bidding, you will have live video streaming. Sell with us it’s free Apply in just 5 minutes. View Copart's salvage car inventory and start bidding on vehicles today. Cars & Bids is the best marketplace for modern enthusiast cars. Salvage-titled vehicles are ideal for individuals looking for a fixer-upper or dismantlers looking for parts. You should also realize that you are not only bidding against people who are presently at the auction location, but also against online bidders. Register to Start Bidding Copart has thousands of salvage vehicles, junk cars available for online auction. The auction is available to view online every Friday after 6:00 p.m.Each Tuesday, bidding begins at 8:30 a.m.Each Tuesday, viewing begins at 8:00 a.m.We do issue an annual bidder card for a fee of $20. Cut in line no waiting to buy your vehicle (this can save a lot of time).Come out to the Auto Auction! Come out to the car auction for your chance to win! 1/14/2024 0 Comments Cloud email archiving solutionsIt can be deployed on-premises, or in a public or private cloud, and uses Single Instance Storage (SIS) to reduce archive storage. It does not install any software on the email server but instead, runs as a virtual appliance offered as VMware OVF, Microsoft Hyper-V, and Amazon Web Services AMI. Make your life easier by using one email archiving solution for full email management control.ĭesigned for single or multi-tenant architectures, Arcserve Email Archiving enables modern email archiving management for multiple divisions, locations, or end users with on-premises or cloud-based platforms such as Microsoft Exchange, IBM Domino, Microsoft Office 365, and Google Gmail. Eliminate time spent counting employees by protecting unlimited mailboxes and only paying for the storage you use. Optimize storage and increase platform performance by storing archived email in a location independent from the primary mail system. Not only must IT staffs protect these records, they must also address rising storage costs and deliver against legal, regulatory, and corporate governance requirements.Īrcserve’s Email Archiving software solution was designed to enable modern email archiving management by equipping you with the capabilities necessary to fully comply with legal and regulatory requirements, while eliminating the cost and hassle of traditional email archiving solutions. Often serving as an organization’s primary written communication channel, 60 billion new emails are created every day and store over half of all confidential business information. Wave goodbye to the "complexity" of email archiving solutions 1/14/2024 0 Comments Price chopper vaccine boostersHowever, the EU has not ordered any more doses after the vaccine was linked with rare blood clots. The AstraZeneca jab is the cheapest of the main Covid-19 vaccines, priced at just $2.15 a dose in the company’s contract with the EU, rising to just over $5 a shot elsewhere. Results from clinical trials are expected later this year. The UK government is in negotiations with AstraZeneca to order a new version of its vaccine adapted to tackle variants of the coronavirus. So far it has shipped 1bn doses globally and is aiming to produce a total of 2bn-3bn jabs this year. Revenue of $1.2bn was achieved by AstraZeneca from the vaccine it developed with the University of Oxford in the first half of the year. The firm has reportedly lifted the price it charges the EU to $25.50 a dose from about $19 in its first deal. Last week the company also said that sales under the Covax vaccine initiative to low-income countries were “considerably lower than the price to the US government”. It has charged the US government (which helped fund the development of the vaccine) up to $16.50 a dose, and has sold it for $22 to $37 outside the US. It expects to produce up to 1bn jabs this year, followed by 2bn-3bn in 2022. Moderna has signed $20bn worth of vaccine contracts this year, including that for 17m doses to the UK, 460m to the EU and 500m to the US. This company generated nearly $6bn of sales from its Covid-19 vaccine in the first half of the year, achieving a $4bn net profit – the first half-year profit since the firm was founded in Massachusetts in 2010. “This means wealthier nations would pay about the cost of a takeaway meal for each dose … middle-income countries would pay roughly half that price … and to low-income countries we were offering them doses at cost.” Moderna Pfizer’s chief executive, Albert Bourla, recently explained the tiered pricing. The UK is also reportedly paying more than previously, about £22 a shot for 35m doses for next year’s autumn booster campaign. They are now charging the EU €19.50 per jab, up from €15.50 in the first procurement deal, the Financial Times reported. Pfizer and BioNTech are aiming to produce 3bn jabs this year and 4bn next year. The US government has ordered 700m up to April next year for Americans, as well as 500m for donations to the poorest nations. The two firms have agreed to supply up to 1.8bn doses to the EU from December up to 2023, on top of 600m doses previously ordered this year. In July it lifted its 2021 sales forecast to $33.5bn.īioNTech expects to make revenues of nearly €16bn (£13.5bn) from the vaccine this year, as its first-half net profit jumped to almost €4bn from €142m a year earlier. Sales worth $11.3bn (£8bn) were made by Pfizer in the first half of this year from the Covid-19 jab that it developed with Germany’s BioNTech. 1/14/2024 0 Comments Nail tip shapesCreate Instagram-worthy nail sets with the help of. Each gelly tip features prominent apex for extra strength, durability, and long-lasting wear. If you’re looking for an easy-to-use and versatile option that doesn’t require much time or energy for a good fit, then well-less tips are. The main three are well-less nail tips, half-well nail tips, and full-well nail tips. Once you get the sides down, start to refine the tip to get your final shape. Our soak-off gel extension selection features a wide assortment of different gel nail tip shapes that range from medium almond to long coffin, medium square, and many other options. You have a couple of different shape and coverage options when it comes to your nail tips. Round-Shaped Nails View full post on Instagram This simple shape is perfect for short nails (even nail biters ), extending only slightly past your nail bed and maintaining its natural. If you have long, narrow nail beds, this nail shape will work well for. With sharp, square corners, this is a popular look for short nails. For best results, file in one direction to lessen the fraying of the nail. They have blunt, straight lines on all sides and come to a flat tip. The square shape nail is a classic for the modernist. Depending on the shape you're going for, you will go more or less narrow. Start shaping by filing the sides down and narrowing them out a bit. Simply push back your cuticles with a cuticle stick to look at your true cuticle shape, then get started. To flatter those tips, you’ll need to find the best nail shape for your hands by figuring out the shape of your cuticle and nail bed. : Mothers Day Gifts Matte Almond and Coffin Nail Tips - Chameleon Gel x Nails 240pcs 2 Shapes Nail Tips for Acrylic Nails Professional Nail tips. Before we get started, take a good look at your hands. The world has more nail shapes than we have fingers, but we’re on hand to help you select the right angles for your nails, so you really can enjoy your perfect mani. 5 BASIC NAIL TIP SHAPES / (English) - YouTube 0:00 / 4:30 5 BASIC NAIL TIP SHAPES / (English) NAILTISFACTION 84.7K subscribers 258K views 4 years ago THIS VIDEO IS SO HELPFUL IF YOU ARE A. It’s the best way to care for the health of your. Nail Care How to Find the Best Nail Shape for Your Hands Looking for ways to give yourself a makeover? Instead of reaching for the scissors and attempting a haircut, why not reach for a file and try a new nail shape? We’ve scoped out the best nail shapes for your hands, with a few tips to guide you along the way. published SeptemTreating yourself to a fresh manicure, whether done by a pro or by yourself, is undoubtedly a self-care staple. 1/14/2024 0 Comments Endurance bike vs cyclocrossA longer head tube results in a more natural upright riding position, ideal for rides where speed isn’t essential. One of the crucial identifiers of endurance bike geometry is looking at the head tube length. They are quite similar and share common features however, there are a few noticeable differences that separate a racing machine from an endurance bike. Despite that, we can pick out a few key indicators of endurance road bikes and assess how they compare to another road bike.īelow, we have the geometry charts for the Propel Advanced pro and the equivalent Defy. It’s tempting to focus on the numbers in isolation, however, the whole package must be considered when comparing bikes as a small change in one area has a huge knock-on effect elsewhere. On first glance, a geometry chart can just look like a load of numbers chucked onto a table however, they are the result of decisions refined over years of experience and manufacturing that lead to the perfectly tuned machines on the road today. They typically attract riders who want to spend long days in the saddle without feeling every bump and vibration from the road at the end of the day.įocusing on the geometry, they aren't as aggressive as race bikes such as our TCR or Propel range. But what does this actually mean?īelow, we look at what goes into making an endurance road bike and the small changes that make a big difference in how the bike feels and rides. Sometimes referred to as a 'sportive bike', the endurance road bike has increased in popularity in the UK as riders look for more comfort when tackling poor road surfaces and adverse weather conditions.Īlthough they look similar on the surface, there are subtle changes to the makeup of the bikes in this category wider tyres, more upright riding position, powerful disc brakes and shorter top tubes are all common features that distinguish endurance road bikes. |
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